Jigoku ni Ochite yo, Onii-chan

Yudai, a college boy, was heartbroken after a premature breakup with his first girlfriend. He was filled with a sense of emptiness, until he met his new step-sister Yuna, who had just moved in after their parents remarried. The feelings were more than just love at first sight. However, Yuna has a big secret...
(Source: Young Gangan, translated)